Issue 18, 2003
From the journal:

Chemical Communications

Synthesis, molecular structure and chemical properties of a new tungstosilicate with an open Wells–Dawson structure, α-[Si2W18O66]16−

Nathalie Laronze,*a   Jérôme Marrota  and  Gilbert Hervéa  

* Corresponding authors

a Institut Lavoisier, Université de Versailles, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
E-mail: laronze@chimie.uvsq.fr
Fax: 33(0)139254381
Tel: 33(0)139254360

Abstract

Acidification of K10A-α-[SiW9O34] in aqueous solution leads to the formation of α-[Si2W18O66]16−, built up from two A-α-{SiW9O34} subunits, which reacts with metal cations to form potassium and mixed potassium–transition metal complexes.

Graphical abstract: Synthesis, molecular structure and chemical properties of a new tungstosilicate with an open Wells–Dawson structure, α-[Si2W18O66]16−

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Article information

DOI
https://doi.org/10.1039/B307276B
Article type
Communication
Submitted
26 Jun 2003
Accepted
28 Jul 2003
First published
12 Aug 2003

Chem. Commun., 2003, 2360-2361

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Synthesis, molecular structure and chemical properties of a new tungstosilicate with an open Wells–Dawson structure, α-[Si2W18O66]16−

N. Laronze, J. Marrot and G. Hervé, Chem. Commun., 2003, 2360 DOI: 10.1039/B307276B

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