Issue 18, 2003
From the journal:

Chemical Communications

Trinuclear and hexanuclear platinum clusters as building blocks for organometallic one-dimensional structures†

Piero Leoni,*a   Fabio Marchetti,a   Lorella Marchettia  and  Marco Pasqualia  

* Corresponding authors

a Dipartimento di Chimica e Chimica Industriale, Via Risorgimento 35, I-56126 Pisa, Italy
E-mail: leoni@dcci.unipi.it
Fax: +39(0)50/20237

Abstract

The reaction between the new hexa- and trinuclear clusters {Pt6}(CC–C6H4–CCH)2, (4) [{Pt6} = Pt6(CO)4(μ-PBut2)4], and {Pt3}Cl, (6) [{Pt3} = Pt3(μ-PBut2)3(CO)2], in CuI/Amine gives the thermally and air stable {Pt6}(CC–C6H4–CC{Pt3})2 (7), where the cluster units are separated by conjugated 1,4-diethynylphenyl groups.

Graphical abstract: Trinuclear and hexanuclear platinum clusters as building blocks for organometallic one-dimensional structures

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Article information

DOI
https://doi.org/10.1039/B307003D
Article type
Communication
Submitted
19 Jun 2003
Accepted
29 Jul 2003
First published
15 Aug 2003

Chem. Commun., 2003, 2372-2373

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Trinuclear and hexanuclear platinum clusters as building blocks for organometallic one-dimensional structures

P. Leoni, F. Marchetti, L. Marchetti and M. Pasquali, Chem. Commun., 2003, 2372 DOI: 10.1039/B307003D

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