Issue 18, 2003
From the journal:

Chemical Communications

Relationship between rate and distance

Fredric M. Menger,*a   Ashley L. Gallowaya  and  Djamaladdin G. Musaev*b  

* Corresponding authors

a Department of Chemistry, Emory University, Atlanta, GA, USA
E-mail: menger@emory.edu

b Cherry L. Emerson Center for Scientific Computation, Emory University, Atlanta, GA, USA
E-mail: dmusaev@emory.edu

Abstract

The activation energies for four Smiles reactions vary with the distance squared between the nucleophilic and electrophilic atoms (consistent with theoretical considerations and pertinent to organic and enzymatic catalyses).

Graphical abstract: Relationship between rate and distance

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Article information

DOI
https://doi.org/10.1039/B306342A
Article type
Communication
Submitted
09 Jun 2003
Accepted
23 Jul 2003
First published
15 Aug 2003

Chem. Commun., 2003, 2370-2371

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Relationship between rate and distance

F. M. Menger, A. L. Galloway and D. G. Musaev, Chem. Commun., 2003, 2370 DOI: 10.1039/B306342A

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