Issue 18, 2003
From the journal:

Chemical Communications

The first structurally characterised perchlorato-cobalt(iii) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane†

Xiangting Zhou,a   Anthony I. Day,a   Anthony C. Willisb  and  W. Gregory Jackson*a  

* Corresponding authors

a School of Chemistry, University College, The University of New South Wales, Australian Defence Force Academy, Canberra ACT 2600, Australia
E-mail: g-jackson@adfa.edu.au
Fax: +61 2 62688090
Tel: +61 2 62688917

b Research School of Chemistry, Australian National University, Canberra ACT 0200, Australia
E-mail: willis@rsc.anu.edu.au
Fax: +62 2 61250750
Tel: +62 2 61254109

Abstract

Two isomeric C-bonded complexes, sym-anti-[Co(L-C)(OH2)]2+ and sym-syn-[Co(L-C)(OH2)]2+ (L = 1,4,8,11-tetraazabicyclo[9.5.2]octadecane) when crystallised from aqueous NaClO4 remarkably yielded the corresponding perchlorato complexes, confirmed by the single crystal X-ray structures.

Graphical abstract: The first structurally characterised perchlorato-cobalt(iii) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

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Article information

DOI
https://doi.org/10.1039/B305182J
Article type
Communication
Submitted
08 May 2003
Accepted
25 Jul 2003
First published
20 Aug 2003

Chem. Commun., 2003, 2386-2387

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The first structurally characterised perchlorato-cobalt(III) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

X. Zhou, A. I. Day, A. C. Willis and W. G. Jackson, Chem. Commun., 2003, 2386 DOI: 10.1039/B305182J

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