Issue 2, 2003
From the journal:

Chemical Communications

Polymer-supported formamides as reusable organocatalysts for allylation of aldehydes with allyltrichlorosilane

Chikako Ogawa,a   Masaharu Sugiuraa  and  Shū Kobayashi*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: skobayas@mol.f.u-tokyo.ac.jp

Abstract

New types of polymer-supported formamides have been synthesized from chloromethylated resins and formamides; it was found that the polymers worked well as organocatalysts in the allylation of aldehydes with allyltrichlorosilane to afford homoallylic alcohols in high yields; the polymers were easily recovered and reused several times without loss of activity.

Graphical abstract: Polymer-supported formamides as reusable organocatalysts for allylation of aldehydes with allyltrichlorosilane

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Article information

DOI
https://doi.org/10.1039/B210826G
Article type
Communication
Submitted
05 Nov 2002
Accepted
02 Dec 2002
First published
20 Dec 2002

Chem. Commun., 2003, 192-193

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Polymer-supported formamides as reusable organocatalysts for allylation of aldehydes with allyltrichlorosilane

C. Ogawa, M. Sugiura and S. Kobayashi, Chem. Commun., 2003, 192 DOI: 10.1039/B210826G

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