Issue 2, 2003
From the journal:

Chemical Communications

An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band

Chad Risko,a   Stephen Barlow,*a   Veaceslav Coropceanu,a   Marcus Halik,a   Jean-Luc Brédas*a  and  Seth R. Marder*a  

* Corresponding authors

a Department of Chemistry, The University of Arizona, Tucson, Arizona, USA
E-mail: sbarlow@email.arizona.edu

Abstract

The reduction of a phenylene-bridged bis(dioxaborine) affords a strongly delocalised organic mixed-valence system; for the first time details of the vibrations coupled to the electron transfer have been extracted from the intervalence band.

Graphical abstract: An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band

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Article information

DOI
https://doi.org/10.1039/B210429F
Article type
Communication
Submitted
24 Oct 2002
Accepted
04 Dec 2002
First published
18 Dec 2002

Chem. Commun., 2003, 194-195

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An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band

C. Risko, S. Barlow, V. Coropceanu, M. Halik, J. Brédas and S. R. Marder, Chem. Commun., 2003, 194 DOI: 10.1039/B210429F

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