Issue 14, 2002

Monocarbaborane anion chemistry. The substantiation of the C-arylated [PhCB6H6] seven-vertex closo cluster anion by single-crystal synchrotron X-ray diffraction analysis

Abstract

Single-crystal synchrotron X-ray diffraction analysis of the [NEt4]+ salt of the [2-Ph-closo-2-CB6H6] anion, obtained from [4-Ph-arachno-4-CB8H13] and NEt3 in refluxing toluene, substantiates the anion as the first structurally characterised seven-vertex monocarbaborane.

Graphical abstract: Monocarbaborane anion chemistry. The substantiation of the C-arylated [PhCB6H6]− seven-vertex closo cluster anion by single-crystal synchrotron X-ray diffraction analysis

Supplementary files

Article information

Article type
Communication
Submitted
23 May 2002
Accepted
13 Jun 2002
First published
21 Jun 2002

J. Chem. Soc., Dalton Trans., 2002, 2807-2808

Monocarbaborane anion chemistry. The substantiation of the C-arylated [PhCB6H6] seven-vertex closo cluster anion by single-crystal synchrotron X-ray diffraction analysis

A. Franken, D. L. Ormsby, C. A. Kilner, W. Clegg, M. Thornton-Pett and J. D. Kennedy, J. Chem. Soc., Dalton Trans., 2002, 2807 DOI: 10.1039/B205016C

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