Issue 14, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide

Stephen J. Archibald,a   Simon P. Foxon,b   Jonathan D. Freeman,b   James E. Hobson,b   Robin N. Perutz*b  and  Paul H. Walton*b  

* Corresponding authors

a Department of Chemistry, University of Hull, Cottingham Road, Hull, England

b Department of Chemistry, University of York, Heslington, York, England
E-mail: phw2@york.ac.uk

Abstract

The complexes [Co(TCT)(OR)]BPh4 (R = Et, Ph; TCT = cis,cis-1,3,5-tris(cinnamylideneamino)cyclohexane) have been prepared and characterised by X-ray diffraction; in coordinating solvents both complexes react reversibly with carbon dioxide to form organocarbonate complexes.

Graphical abstract: Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide

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Article information

DOI
https://doi.org/10.1039/B204560E
Article type
Communication
Submitted
13 May 2002
Accepted
12 Jun 2002
First published
21 Jun 2002

J. Chem. Soc., Dalton Trans., 2002, 2797-2799

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Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide

S. J. Archibald, S. P. Foxon, J. D. Freeman, J. E. Hobson, R. N. Perutz and P. H. Walton, J. Chem. Soc., Dalton Trans., 2002, 2797 DOI: 10.1039/B204560E

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