Issue 14, 2002

Synthesis, characterisation and reactivity of a novel iridaphosphirene complex, [Ir{[double bond, length half m-dash]C(But)P(Cy)}(CO)(PPh3)2], Cy = cyclohexyl

Abstract

The reaction of the phosphavinyl Grignard reagent, [CyP[double bond, length as m-dash]C(But)MgCl(OEt2)], Cy = cyclohexyl, with Vaska's compound affords the first example of an iridaphosphirene complex, [Ir{[double bond, length half m-dash]C(But)P(Cy)}(CO)(PPh3)2], which has been crystallographically characterised and its reaction with CO examined.

Graphical abstract: Synthesis, characterisation and reactivity of a novel iridaphosphirene complex, [Ir{ [[double bond, length half m-dash]] C(But)P(Cy)}(CO)(PPh3)2], Cy = cyclohexyl

Supplementary files

Article information

Article type
Communication
Submitted
29 Apr 2002
Accepted
10 Jun 2002
First published
18 Jun 2002

J. Chem. Soc., Dalton Trans., 2002, 2800-2801

Synthesis, characterisation and reactivity of a novel iridaphosphirene complex, [Ir{[double bond, length half m-dash]C(But)P(Cy)}(CO)(PPh3)2], Cy = cyclohexyl

M. Brym, C. Jones and A. F. Richards, J. Chem. Soc., Dalton Trans., 2002, 2800 DOI: 10.1039/B204127H

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