Issue 14, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, structure and chemistry of vanadium(iv) and vanadium(v) compounds with substituted hydrazido(1−) and hydrazido(2−) ligands

Sian C. Davies,a   David L. Hughes,a   Martin Konkol,b   Raymond L. Richards,c   J. Roger Sandersa  and  Piotr Sobotac  

a Department of Biological Chemistry, John Innes Centre, Norwich, UK

b Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie Street, Wroclaw, Poland

c School of Chemistry, Physics and Environmental Science, University of Sussex, Brighton, UK

Abstract

The reaction of [V(NS3)O] [NS3 = N(CH2CH2S)3] with methylhydrazine gives the hydrazido(1−) vanadium(IV) complex [V(NS3)(NMeNH2)] 1, but reaction with various other compounds containing N–N groups results in formation of compounds containing substituted hydrazido(2−) ligands. Structures of 1, [V(NS3)(NNC5H10)] 2 and [V(NS3)(NNCPh2)] 3 are described.

Graphical abstract: Synthesis, structure and chemistry of vanadium(iv) and vanadium(v) compounds with substituted hydrazido(1−) and hydrazido(2−) ligands

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Article information

DOI
https://doi.org/10.1039/B202098J
Article type
Paper
Submitted
27 Feb 2002
Accepted
02 May 2002
First published
10 Jun 2002

J. Chem. Soc., Dalton Trans., 2002, 2811-2814

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Synthesis, structure and chemistry of vanadium(IV) and vanadium(V) compounds with substituted hydrazido(1−) and hydrazido(2−) ligands

S. C. Davies, D. L. Hughes, M. Konkol, R. L. Richards, J. R. Sanders and P. Sobota, J. Chem. Soc., Dalton Trans., 2002, 2811 DOI: 10.1039/B202098J

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