Issue 13, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]·2H2O}∞

José-Ramón Galán-Mascarós,a   Juan-Modesto Clemente-Juanb  and  Kim R. Dunbar*a  

* Corresponding authors

a Department of chemistry, Texas A&M University, College Station, TX 77842-3012, USA
E-mail: dunbar@mail.chem.tamu.edu

b Instituto de Ciencia Molecular, Universidad de Valencia, Dr. Moliner, 50. 46100, Burjassot, Spain

Abstract

The one-dimensional chain compound {[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]}n−n was obtained from a reaction of 1,3,5-triazine-2,4,6-tricarboxylate with Fe(II) in water at room temperature. The high-spin Fe(II) centers adopt a pentagonal bipyramid geometry with unusual ligand binding modes. Magnetic measurements revealed weak magnetic interactions between paramagnetic centers; these were modeled with both axial and rhombic distortions.

Graphical abstract: Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]·2H2O}∞

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Article information

DOI
https://doi.org/10.1039/B109585B
Article type
Paper
Submitted
03 Oct 2001
Accepted
18 Apr 2002
First published
20 May 2002

J. Chem. Soc., Dalton Trans., 2002, 2710-2713

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Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]·2H2O}∞

J. Galán-Mascarós, J. Clemente-Juan and K. R. Dunbar, J. Chem. Soc., Dalton Trans., 2002, 2710 DOI: 10.1039/B109585B

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