Issue 24, 2002
From the journal:

Chemical Communications

Synthesis and structure of a novel supramolecular Zn3Co8assembly containing a linear Zn3 core†

Lilu Zhang,a   Richard A. Jones*a  and  Vincent M. Lyncha  

* Corresponding authors

a The University of Texas at Austin, Chem & Biochem Dept, University Station A5300, Austin, Texas, USA
E-mail: rajones@mail.utexas.edu
Tel: 512 471 1706

Abstract

Reaction of Zn(OAc)2·2H2O (OAc = acetate) with LH2 in THF followed by reaction with Co2(CO)8 yields the novel supramolecular assembly Zn3L2(OAc)2[Co2(CO)6]4·0.5CH2Cl2, which was characterized by X-ray diffraction (LH2 = (CH2)3(N[double bond, length as m-dash]CH-2-OH-5-C[triple bond, length as m-dash]CSiMe3C6H3)2 or N,N′-propylenebis(2-hydroxy-5-trimethylsilylethynl-1-aldimine).

Graphical abstract: Synthesis and structure of a novel supramolecular Zn3Co8 assembly containing a linear Zn3 core

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Article information

DOI
https://doi.org/10.1039/B209785K
Article type
Communication
Submitted
03 Oct 2002
Accepted
29 Oct 2002
First published
18 Nov 2002

Chem. Commun., 2002, 2986-2987

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Synthesis and structure of a novel supramolecular Zn3Co8 assembly containing a linear Zn3 core

L. Zhang, R. A. Jones and V. M. Lynch, Chem. Commun., 2002, 2986 DOI: 10.1039/B209785K

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