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Issue 17, 2002
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Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

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Abstract

Four-coordinate iron(II) complexes bearing α-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive β-hydrogen chain transfer processes.

Graphical abstract: Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

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Publication details

The article was received on 10 May 2002, accepted on 12 Jul 2002 and first published on 24 Jul 2002


Article type: Communication
DOI: 10.1039/B204510A
Citation: Chem. Commun., 2002,0, 1850-1851

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    Four-coordinate iron complexes bearing α-diimine ligands: efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

    V. C. Gibson, R. K. O’Reilly, W. Reed, D. F. Wass, A. J. P. White and D. J. Williams, Chem. Commun., 2002, 0, 1850
    DOI: 10.1039/B204510A

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