Issue 16, 2002
From the journal:

Chemical Communications

Structure and reactivity of a novel parallel thiosulfito (SSO2-S∶S′) rhodium dinuclear complex

Kimie Shiomi,a   Brian K. Breedlove,*a   Hiroaki Kitayama,a   Takanori Nishioka,*a   Isamu Kinoshita,a   Nobuaki Kogab  and  Kiyoshi Isobea  

* Corresponding authors

a Department of Material Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku Osaka, Japan
E-mail: nishioka@sci.osaka-cu.ac.jp
Fax: 81-6-6690-2753
Tel: 81-6-6605-2546

b Graduate School of Human Informatics, Nagoya University, Nagoya, Japan

Abstract

The parallel thiosulfite ligand (SSO2) in a rhodium complex, which is formed by oxygenation of a bridging disulfide, is converted to a bridging hydrocarbyl thiolate ligand and sulfur dioxide gas by the reaction with hydrocarbyl halides.

Graphical abstract: Structure and reactivity of a novel parallel thiosulfito (SSO2-S∶S′) rhodium dinuclear complex

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Article information

DOI
https://doi.org/10.1039/B204765A
Article type
Communication
Submitted
16 May 2002
Accepted
01 Jul 2002
First published
12 Jul 2002

Chem. Commun., 2002, 1756-1757

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Structure and reactivity of a novel parallel thiosulfito (SSO2-S∶S′) rhodium dinuclear complex

K. Shiomi, B. K. Breedlove, H. Kitayama, T. Nishioka, I. Kinoshita, N. Koga and K. Isobe, Chem. Commun., 2002, 1756 DOI: 10.1039/B204765A

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