Issue 14, 2002

New phases of sp2-bonded boron nitride: the 12R and 24R polytypes

Abstract

sp2-Bonded polytypes of graphite-like boron nitride are evidenced in the approximately twin-related bicrystal-like BN nanofibres synthesized by a high-temperature substitution reaction between carbon nanofibres and boron oxides in N2 atmosphere; the material shows a main 12R phase of A′ABC/C′CAB/B′BCA packing and a minor 24R phase with an A′ABC/BB′C′A′/C′CAB/… packing sequence.

Graphical abstract: New phases of sp2-bonded boron nitride: the 12R and 24R polytypes

Article information

Article type
Communication
Submitted
04 Apr 2002
Accepted
30 May 2002
First published
11 Jun 2002

Chem. Commun., 2002, 1490-1491

New phases of sp2-bonded boron nitride: the 12R and 24R polytypes

F. F. Xu, Y. Bando and M. Hasegawa, Chem. Commun., 2002, 1490 DOI: 10.1039/B203144B

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