Issue 14, 2002

[VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (MIL-59): a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework

Abstract

[VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (denoted MIL-59) presents a three-dimensional framework built up from octahedral vanadium trimers joined via the isophthalate anionic linkers to delimit cages where water molecules and chlorine anions are occluded; the frustrated magnetic behaviour of MIL-59 is discussed.

Graphical abstract: [VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (MIL-59): a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework

Supplementary files

Article information

Article type
Communication
Submitted
19 Mar 2002
Accepted
28 May 2002
First published
11 Jun 2002

Chem. Commun., 2002, 1492-1493

[VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (MIL-59): a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework

K. Barthelet, D. Riou and G. Férey, Chem. Commun., 2002, 1492 DOI: 10.1039/B202749F

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