Issue 10, 2002
From the journal:

Chemical Communications

Structure and reactivity studies of the first tungsten cyanoalkylidene complex†

Thomas M. Cameron,a   A. Scott Gamble,a   Khalil A. Abbouda  and  James M. Boncella*a  

* Corresponding authors

a Department of Chemistry and Centre for Catalysis, University of Florida, Gainesville, FL, USA
E-mail: boncella@chem.ufl.edu

Abstract

Alkylidene complex W(CHCMe2Ph)(NAr)[OCMe(CF3)2]2 (Ar = 2, 6 diisopropylphenyl) (4) reacts with one equivalent of acrylonitrile in methylene chloride to afford the tetrameric, cyanoalkylidene complex [W(CHCN)(NAr)[OCMe(CF3)2]2]4 (5) which reacts with excess acetonitrile to give the tetrameric complex [W(N(H)C(CH3)C(CN)C(CH3)N)(NAr)[OCMe(CF3)2]2]4 (6).

Graphical abstract: Structure and reactivity studies of the first tungsten cyanoalkylidene complex

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Article information

DOI
https://doi.org/10.1039/B202110B
Article type
Communication
Submitted
28 Feb 2002
Accepted
04 Apr 2002
First published
25 Apr 2002

Chem. Commun., 2002, 1148-1149

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Structure and reactivity studies of the first tungsten cyanoalkylidene complex

T. M. Cameron, A. S. Gamble, K. A. Abboud and J. M. Boncella, Chem. Commun., 2002, 1148 DOI: 10.1039/B202110B

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