Issue 10, 2002
From the journal:

Chemical Communications

A novel and efficient chiral palladium–phosphinooxazolidine catalyst for the enantioselective Diels–Alder reaction†

Hiroto Nakano,*a   Yuko Okuyama,a   Yuichiro Suzuki,a   Reiko Fujitaa  and  Chizuko Kabuto*b  

* Corresponding authors

a Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai, Japan
E-mail: hnakano@tohoku-pharm.ac.jp
Fax: 81 22 275 2013
Tel: 81 22 234 4181

b Instrumental Analysis Center for Chemistry, Graduate School of Science, Tohoku University, Aoba, Aramaki, Aoba-ku, Sendai, Japan
E-mail: kabuto@kiki.chem.tohoku.ac.jp

Abstract

Easily prepared, chiral cationic palladium(II)–phosphinooxazolidine complexes are described which give excellent enantioselectivity (up to 98% ee) in the Diels–Alder reaction of cyclopentadiene with a range of acyl-1,3-oxazolidin-2-one dienophiles.

Graphical abstract: A novel and efficient chiral palladium–phosphinooxazolidine catalyst for the enantioselective Diels–Alder reaction

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Article information

DOI
https://doi.org/10.1039/B201625G
Article type
Communication
Submitted
13 Feb 2002
Accepted
02 Apr 2002
First published
19 Apr 2002

Chem. Commun., 2002, 1146-1147

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A novel and efficient chiral palladium–phosphinooxazolidine catalyst for the enantioselective Diels–Alder reaction

H. Nakano, Y. Okuyama, Y. Suzuki, R. Fujita and C. Kabuto, Chem. Commun., 2002, 1146 DOI: 10.1039/B201625G

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