Issue 6, 2002
From the journal:

Chemical Communications

Evidence of an equilibrium between selenides and osmium(viii) reagents and selenoxides and osmium(vi) reagents

Alain Krief,*a   Alexandra Destree,b   Virginie Durisotti,b   Nicolas Moreau,b   Caroline Smalb  and  Catherine Colaux-Castilloa  

* Corresponding authors

a Laboratoire de Chimie Organique de Synthèse, Département de Chimie, Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, Namur, Belgium
E-mail: alain.krief@fundp.ac.be
Fax: +32 8172 4536
Tel: +32 8172 4539

b Laboratoire de Travaux Pratiques de Chimie Organique 1iere Licence, Département de Chimie, Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, Namur, Belgium

Abstract

Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C[double bond, length as m-dash]C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7-dihydroxy citronellyl selenide.

Graphical abstract: Evidence of an equilibrium between selenides and osmium(viii) reagents and selenoxides and osmium(vi) reagents

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Article information

DOI
https://doi.org/10.1039/B109420N
Article type
Communication
Submitted
16 Oct 2001
Accepted
29 Jan 2002
First published
15 Feb 2002

Chem. Commun., 2002, 558-559

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Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents

A. Krief, A. Destree, V. Durisotti, N. Moreau, C. Smal and C. Colaux-Castillo, Chem. Commun., 2002, 558 DOI: 10.1039/B109420N

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