Issue 23, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Novel organic-solvent-free aziridination of olefins: Chloramine-T–I2 system under phase-transfer catalysis conditions

Daisuke Kano,a   Satoshi Minakata*a  and  Mitsuo Komatsu*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan

Abstract

A variety of olefins could be aziridinated successfully by employing iodine-catalysed aziridination in water with a catalytic amount of a quaternary ammonium salt. Furthermore, the larger-scale process of styrene aziridination gives a highly pure aziridine in good yield via simple work-up.

Graphical abstract: Novel organic-solvent-free aziridination of olefins: Chloramine-T–I2 system under phase-transfer catalysis conditions

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Article information

DOI
https://doi.org/10.1039/B104940M
Article type
Paper
Submitted
05 Jun 2001
Accepted
31 Oct 2001
First published
19 Nov 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 3186-3188

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Novel organic-solvent-free aziridination of olefins: Chloramine-T–I2 system under phase-transfer catalysis conditions

D. Kano, S. Minakata and M. Komatsu, J. Chem. Soc., Perkin Trans. 1, 2001, 3186 DOI: 10.1039/B104940M

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