Issue 11, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

A novel utilization of trifluoromethanide as a base: a convenient synthesis of trimethylsilylacetylene

Mitsuhiro Yoshimatsu*a  and  Masako Kuribayashia  

* Corresponding authors

a Department of Chemistry, Faculty of Education, Gifu University, Yanagido 1-1, Gifu, Japan
E-mail: yoshimae@cc.gifu-u.ac.jp
Fax: +81-058-293-2207

Abstract

Trifluoromethanide generated from CF3SiMe3–Bu4NF reacted with terminal acetylenes and acetylenic selenides as a base or a nucleophile to give trimethylsilylacetylenes in high yields.

Graphical abstract: A novel utilization of trifluoromethanide as a base: a convenient synthesis of trimethylsilylacetylene

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Article information

DOI
https://doi.org/10.1039/B101537K
Article type
Communication
Submitted
16 Feb 2001
Accepted
25 Apr 2001
First published
11 May 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 1256-1257

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A novel utilization of trifluoromethanide as a base: a convenient synthesis of trimethylsilylacetylene

M. Yoshimatsu and M. Kuribayashi, J. Chem. Soc., Perkin Trans. 1, 2001, 1256 DOI: 10.1039/B101537K

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