Issue 3, 2001

Unusual chemoselective addition of diisopropylzinc to 2,2′-bipyridine-5,5′-dicarbonyl compounds in the 2-position and autoxidative reconversion with carbon–carbon bond cleavage

Abstract

Unusual chemoselective addition of diisopropylzinc to the 2-position of 2,2′-bipyridine-5,5′-dicarbonyl compounds affords the adducts with a quaternary carbon, and autoxidation of the adducts reconverts them into the initial compounds with carbon–carbon bond cleavage.

Graphical abstract: Unusual chemoselective addition of diisopropylzinc to 2,2′-bipyridine-5,5′-dicarbonyl compounds in the 2-position and autoxidative reconversion with carbon–carbon bond cleavage

Article information

Article type
Communication
Submitted
27 Nov 2000
Accepted
20 Dec 2000
First published
11 Jan 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 217-218

Unusual chemoselective addition of diisopropylzinc to 2,2′-bipyridine-5,5′-dicarbonyl compounds in the 2-position and autoxidative reconversion with carbon–carbon bond cleavage

S. Tanji, T. Shibata, I. Sato and K. Soai, J. Chem. Soc., Perkin Trans. 1, 2001, 217 DOI: 10.1039/B009474I

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