Various multicyclic and bridged 1,4-diketones were subjected to the reductive conditions of the SmI2–HMPA system, often affording surprising results and reactivity upon fragmentation of the 2,3 C–C bond to provide the corresponding ring enlarged product.
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D. B. G. Williams, K. Blann and C. W. Holzapfel, J. Chem. Soc., Perkin Trans. 1, 2001, 219 DOI: 10.1039/B008110H
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