Issue 24, 2001
From the journal:

Chemical Communications

Kinetic resolution of secondary alcoholsvia chiral Pd(ii)-complex-catalysed enantioselective benzoylation using CO and organobismuth(v) compound

Yoshihiro Miyake,a   Tomochika Iwata,a   Kang-Go Chung,a   Yoshiaki Nishibayashia  and  Sakae Uemura*a  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto, Japan.
E-mail: uemura@scl.kyoto-u.ac.jp

Abstract

A novel method for kinetic resolution of racemic secondary alcohols via their enantioselective benzoylation (up to 48% ee) has been explored using CO, Ph3Bi(OAc)2, a catalytic amount of chiral Pd(II)-complex and AgOAc.

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Article information

DOI
https://doi.org/10.1039/B107904B
Article type
Communication
Submitted
05 Sep 2001
Accepted
30 Oct 2001
First published
23 Nov 2001

Chem. Commun., 2001, 2584-2585

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Kinetic resolution of secondary alcohols via chiral Pd(II)-complex-catalysed enantioselective benzoylation using CO and organobismuth(V) compound

Y. Miyake, T. Iwata, K. Chung, Y. Nishibayashi and S. Uemura, Chem. Commun., 2001, 2584 DOI: 10.1039/B107904B

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