Issue 11, 2001
From the journal:

Chemical Communications

A comparative study of an MCM-41 anchored quaternary ammonium chloride/SnCl4 catalyst and its silica gel analogue

T. M. Jyothi,a   M. L. Kaliya,a   M. Herskowitza  and  M. V. Landau*a  

* Corresponding authors

a Blechner Center for Industrial Catalysis and Process Development, Dept. of Chemical Engineering, Ben Gurion University of Negev, Beer Sheva-, Israel.
E-mail: mlandau@bgumail.bgu.ac.il

Abstract

A novel reusable Lewis acid catalyst has been prepared by the heterogenization of a Lewis acid/tetrapropylammonium adduct; anchoring of tin chloride on quaternary ammonium chloride functionalized MCM-41 yielded a catalyst with higher activity compared to the corresponding silica analogue in terms of turnover rates and product yield in the Prins condensation of isobutene and formaldehyde to isoprenol.

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Article information

DOI
https://doi.org/10.1039/B101843O
Article type
Communication
Submitted
27 Feb 2001
Accepted
19 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 992-993

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A comparative study of an MCM-41 anchored quaternary ammonium chloride/SnCl4 catalyst and its silica gel analogue

T. M. Jyothi, M. L. Kaliya, M. Herskowitz and M. V. Landau, Chem. Commun., 2001, 992 DOI: 10.1039/B101843O

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