Issue 11, 2001
From the journal:

Chemical Communications

Synthesis and structure of [Sn9(Ndmp)7(HNdmp)2O2], containing a bidentate double-cubaneoxo fragment (H2Ndmp= 2-amino- 4,6-dimethoxypyrimidine

Neil Feeder,a   Eilís A. Harron,a   Marta E. G. Mosquera,a   Anthony D. Woodsa  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cus.cam.ac.uk

Abstract

The reaction of Sn(NMe2)2 with H2Ndmp (H2Ndmp = 2-amino-4,6-dimethoxypyrimidine) and H2O (ca. 4∶4∶1 equivalents, respectively) gives the cage complex [Sn9(Ndmp)7(HNdmp)2O2] 1, containing an oxo double-cubane fragment [Sn7(Ndmp)6O2] coordinated to a neutral (HNdmpSn)2(μ-Ndmp) unit; 1 is the largest imido Sn(II) complex so far characterised.

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Article information

DOI
https://doi.org/10.1039/B101247I
Article type
Communication
Submitted
07 Feb 2001
Accepted
19 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 1010-1011

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Synthesis and structure of [Sn9(Ndmp)7(HNdmp)2O2], containing a bidentate double-cubane oxo fragment (H2Ndmp= 2-amino- 4,6-dimethoxypyrimidine

N. Feeder, E. A. Harron, M. E. G. Mosquera, A. D. Woods and D. S. Wright, Chem. Commun., 2001, 1010 DOI: 10.1039/B101247I

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