Issue 11, 2001

A multidentate phosphinoalkoxide ligand as a building block in mixed polylithium aggregates

Abstract

The tris(dimethylphosphinomethyl)-substituted lithium alkoxide [LiOC(CH2PMe2)3] acts as a building block in mixed polylithium aggregates, effectively capping triangular Li3 polyhedral faces; it further reacts with lithium organyls to yield the Y-conjugated, symmetrically tris(dimethylphosphino)-substituted trimethylenemethane dianion.

Supplementary files

Article information

Article type
Communication
Submitted
19 Dec 2000
Accepted
26 Apr 2001
First published
15 May 2001

Chem. Commun., 2001, 1024-1025

A multidentate phosphinoalkoxide ligand as a building block in mixed polylithium aggregates

A. Feustel and G. Müller, Chem. Commun., 2001, 1024 DOI: 10.1039/B010115J

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