Issue 4, 2001
From the journal:

Chemical Communications

Palladium–tetraphosphine catalysed cross coupling of aryl bromides with arylboronic acids: remarkable influence of the nature of the

Marie Feuerstein,a   Dorothée Laurenti,a   Céline Bougeant,a   Henri Doucet*a  and  Maurice Santelli*a  

* Corresponding authors

a Laboratoire de Synthèse Organique associé au CNRS, Faculté des Sciences de Saint Jérôme, Avenue Escardrille Normandie-Niemen, Marseille Cedex 20, France.
E-mail: henri.doucet@lso.u-3mrs.fr, m.santelli@lso.u-3mrs.fr;
Fax: 04 91 98 38 65

Abstract

The cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane –[PdCl(C3H5)]2 system catalyses the cross coupling of aryl bromides with arylboronic acids with very high substrate–catalyst ratios in good yields; a turnover number of 28000000 can be obtained for the addition of 4-bromobenzophenone to benzeneboronic acid in the presence of this catalyst.

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Article information

DOI
https://doi.org/10.1039/B009520F
Article type
Communication
Submitted
27 Nov 2000
Accepted
12 Jan 2001
First published
31 Jan 2001

Chem. Commun., 2001, 325-326

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Palladium–tetraphosphine catalysed cross coupling of aryl bromides with arylboronic acids: remarkable influence of the nature of the ligand

M. Feuerstein, D. Laurenti, C. Bougeant, H. Doucet and M. Santelli, Chem. Commun., 2001, 325 DOI: 10.1039/B009520F

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