Issue 4, 2001
From the journal:

Chemical Communications

Synthesis and structure of the [MnIV(biguanide)3]4+ ion: the simplest source for water-stable manganese(iv)

Gopal Das,a   Parimal K. Bharadwaj,a   Debjani Ghosh,b   Beauty Chaudhurib  and  Rupendranath Banerjee*b  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Kanpur, India

b Department of Chemistry, Jadavpur University, Calcutta, India.
E-mail: dsthcr28@cal2.vsnl.net.in

Abstract

Aqueous oxidation of alkaline biguanide sulfate with KMnO4 followed by crystallisation from 2 M HNO3 yields the mononuclear [Mn(bigH)3]4+ ion, which has been characterised crystallographically and provides an easy route to mononuclear, water-stable manganese(IV).

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DOI
https://doi.org/10.1039/B007013K
Article type
Communication
Submitted
29 Aug 2000
Accepted
04 Jan 2001
First published
01 Feb 2001

Chem. Commun., 2001, 323-324

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Synthesis and structure of the [MnIV(biguanide)3]4+ ion: the simplest source for water-stable manganese(IV)

G. Das, P. K. Bharadwaj, D. Ghosh, B. Chaudhuri and R. Banerjee, Chem. Commun., 2001, 323 DOI: 10.1039/B007013K

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