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Issue 21, 2000
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Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

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Abstract

The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels–Alder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g.25–27) embodying the ABC-ring system associated with spinosyns A (1) and D (2).

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Article information


Submitted
17 Aug 2000
Accepted
21 Sep 2000
First published
12 Oct 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 3555-3558
Article type
Communication

Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

M. Banwell, D. Hockless, B. Jarrott, B. Kelly, A. Knill, R. Longmore and G. Simpson, J. Chem. Soc., Perkin Trans. 1, 2000, 3555
DOI: 10.1039/B006759H

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