Issue 1, 2000
From the journal:

Mendeleev Communications

Tunnelling effects in the oxidative addition of a dihydrogen molecule to the palladium ethylenediphosphine complexes [H2P(CH2)2PH2]Pd and [H2P(CH2)2PH2]Pd2

Viktor M. Mamaev,   Igor P. Gloriozov,   Vahan V. Simonyan,   Elena V. Zernova,   Eugene M. Myshakin  and  Yuri V. Babin  

Abstract

In terms of the reaction-path Hamiltonian formalism, the ligand environment has been found to have almost no effect on the activation barrier in the oxidative addition of H2 to the title complexes (the under-barrier tunnelling in the reaction was predominant at T<230 K).

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Article information

DOI
https://doi.org/10.1070/MC2000v010n01ABEH001205
Article type
Paper

Mendeleev Commun., 2000,10, 12-14

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Tunnelling effects in the oxidative addition of a dihydrogen molecule to the palladium ethylenediphosphine complexes [H2P(CH2)2PH2]Pd and [H2P(CH2)2PH2]Pd2

V. M. Mamaev, I. P. Gloriozov, V. V. Simonyan, E. V. Zernova, E. M. Myshakin and Y. V. Babin, Mendeleev Commun., 2000, 10, 12 DOI: 10.1070/MC2000v010n01ABEH001205

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