Issue 24, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Mononuclear gold(I) complex of a chiral tetra(tertiary phosphine). Crystal and molecular structure of [T-4-(RP*,RP*)]-(±)-1,2-bis[(2-diphenylphosphinophenyl)methylphosphino]benzene-P,P′,P′′,P′′′gold(I) hexafluorophosphate

Swarup Chatterjee,a   Felicity K. E. Moore,a   Geoffrey Salem,a   Paul Waringb  and  Anthony C. Willisc  

a Chemistry Department, The Faculties, Australian National University, Canberra, A. C. T., Australia
E-mail: Geoff.Salem@anu.edu.au

b John Curtin School of Medical Research, Australian National University, Canberra, A. C. T., Australia

c Research School of Chemistry, Australian National University, Canberra, A. C. T., Australia

Abstract

A mononuclear tetra(tertiary phosphine)gold(I) complex has been isolated via the reaction of (RP*,RP*)-1,2-bis[(2-dimethylphosphinophenyl)methylphosphino]benzene, (RP*,RP*)-TPP4, with NBun4[AuI2] in ethanol followed by metathesis with aqueous NH4PF6; as confirmed by a crystal structure determination of [Au{(RP*,RP*)-TPP4}]PF6.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B007363F
Article type
Communication
Submitted
11 Sep 2000
Accepted
15 Nov 2000
First published
30 Nov 2000

J. Chem. Soc., Dalton Trans., 2000, 4487-4489

Permissions

Request permissions

Mononuclear gold(I) complex of a chiral tetra(tertiary phosphine). Crystal and molecular structure of [T-4-(RP*,RP*)]-(±)-1,2-bis[(2-diphenylphosphinophenyl)methylphosphino]benzene-P,P′,P′′,P′′′gold(I) hexafluorophosphate

S. Chatterjee, F. K. E. Moore, G. Salem, P. Waring and A. C. Willis, J. Chem. Soc., Dalton Trans., 2000, 4487 DOI: 10.1039/B007363F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements