Issue 12, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

cis-2,4-Diamino-2,4-dichloro-1,3-bis(di-tert-butylmethylsilyl)-cyclodisilazane—synthesis and crystal structure

Bettina Jaschke,a   Regine Herbst-Irmer,a   Uwe Klingebiel*a  and  Thomas Papea  

* Corresponding authors

a Institut für Anorganische Chemie Universität, Tammannstr. 4, Göttingen, Germany
E-mail: uklinge@gwdg.de

Abstract

The reaction between the cyclodisilazane [Cl2Si–NSiMe(CMe3)2]2 and NH3 afforded the first cis-2,4-diamino-2,4-dichloro-1,3-bis(di-tert-butylmethylsilyl)cyclodisilazane [Cl(H2N)Si–NSiMe(CMe3)2]21; the nitrogen of the NH2 group has a planar environment and the shortest Si–NH2 bond length found so far in an aminosilane (167.1 pm).

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Article information

DOI
https://doi.org/10.1039/B002634O
Article type
Communication
Submitted
03 Apr 2000
Accepted
11 May 2000
First published
26 May 2000

J. Chem. Soc., Dalton Trans., 2000, 1827-1828

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cis-2,4-Diamino-2,4-dichloro-1,3-bis(di-tert-butylmethylsilyl)-cyclodisilazane—synthesis and crystal structure

B. Jaschke, R. Herbst-Irmer, U. Klingebiel and T. Pape, J. Chem. Soc., Dalton Trans., 2000, 1827 DOI: 10.1039/B002634O

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