Issue 8, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Hydrotris[3-(carboxypyrrolidido)pyrazol-1-yl]borate, the first proven N3O3-hexadentate homoscorpionate ligand

Arnold L. Rheingold,a   Christopher D. Incarvitoa  and  Swiatoslaw Trofimenko*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Delaware, Newark, USA

Abstract

The new homoscorpionate ligand, hydrotris[3-(carboxypyrrolidido)pyrazol-1-yl]borate, [Tpcpd]−, was synthesized, and it formed with lanthanide(III) ions La, Nd and Sm, structurally characterized [M(Tpcpd)2]PF6 complexes, where the lanthanide ion was in a ten-coordinate enviroment consisting of one N3O3 hexadentate Tpcpd ligand, and one N2O2 tetradentate Tpcpd ligand.

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Article information

DOI
https://doi.org/10.1039/B001651I
Article type
Communication
Submitted
29 Feb 2000
Accepted
02 Mar 2000
First published
30 Mar 2000

J. Chem. Soc., Dalton Trans., 2000, 1233-1234

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Hydrotris[3-(carboxypyrrolidido)pyrazol-1-yl]borate, the first proven N3O3-hexadentate homoscorpionate ligand

A. L. Rheingold, C. D. Incarvito and S. Trofimenko, J. Chem. Soc., Dalton Trans., 2000, 1233 DOI: 10.1039/B001651I

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