Hydrothermal synthesis of two-dimensional organic–inorganic hybrid materials of the nickel–molybdate family: the structures of [{Ni(3,3′-bpy)2}2Mo4O14] and [Ni(3,3′-Hbpy)Mo4O13(OH)]

Robert L. LaDuca, Jr.; Matthew Desciak; Matthew Laskoski; Randy S. Rarig, Jr.; Jon Zubieta

doi:10.1039/B001419M

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Hydrothermal synthesis of two-dimensional organic–inorganic hybrid materials of the nickel–molybdate family: the structures of [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] and [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)]

Robert L. LaDuca, Jr.,*^a Matthew Desciak,^a Matthew Laskoski,^a Randy S. Rarig, Jr.^b and Jon Zubieta*^b

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^a Department of Chemistry and Physics, King’s College, Wilkes-Barre, USA

^b Department of Chemistry, Syracuse University, Syracuse, USA

Abstract

The hydrothermal chemistry of the Ni(II)/molybdate/3,3′-bipyridine system exhibits pronounced pH dependence, such that under basic conditions a 2-D material with embedded clusters [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] 1 is observed, while under acidic conditions the 2-D bimetallic oxide network of [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)] 2 is isolated.

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DOI: https://doi.org/10.1039/B001419M
Article type: Communication
Submitted: 12 Feb 2000
Accepted: 07 Jun 2000
First published: 30 Jun 2000

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J. Chem. Soc., Dalton Trans., 2000, 2255-2257

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Hydrothermal synthesis of two-dimensional organic–inorganic hybrid materials of the nickel–molybdate family: the structures of [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] and [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)]

R. L. LaDuca, Jr., M. Desciak, M. Laskoski, R. S. Rarig, Jr. and J. Zubieta, J. Chem. Soc., Dalton Trans., 2000, 2255 DOI: 10.1039/B001419M

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Journal of the Chemical Society, Dalton Transactions

Hydrothermal synthesis of two-dimensional organic–inorganic hybrid materials of the nickel–molybdate family: the structures of [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] and [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)]

Abstract

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Hydrothermal synthesis of two-dimensional organic–inorganic hybrid materials of the nickel–molybdate family: the structures of [{Ni(3,3′-bpy)₂}₂Mo₄O₁₄] and [Ni(3,3′-Hbpy)Mo₄O₁₃(OH)]

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