Issue 7, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

The first palladium(II) complexes containing arsino(phosphino)methanes as ligands†

Ulrich Schmidt,a   Kerstin Ilga  and  Helmut Werner*a  

* Corresponding authors

a Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, Würzburg, Germany
E-mail: helmut.werner@mail.uni-wuerzburg.de

Abstract

Treatment of [PdCl2(R2AsCH2PPri2)] (3a,b) with AgPF6 leads, depending on the reaction conditions, either to the formation of [{Pd(μ-Cl)(κ2As,P-R2AsCH2PPri2)}2](PF6)2 (4a,b) or [Pd(CH3CN)2(κ2As,P-R2AsCH2PPri2)](PF6)2 (5a,b); the methyl derivative [Pd(Me)(Cl)(But2AsCH2PPri2)] (7) reacts with Na[B(ArF)4] (ArF = C6H3(CF3)2-3,5) to afford the complex [Pd2(Me)2(μ-Cl)(μ-But2AsCH2PPri2)2][B(ArF)4] (8) of the A-frame type, which was characterized by X-ray structure analysis.

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Article information

DOI
https://doi.org/10.1039/B001237H
Article type
Communication
Submitted
15 Feb 2000
Accepted
02 Mar 2000
First published
20 Mar 2000

J. Chem. Soc., Dalton Trans., 2000, 1005-1007

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The first palladium(II) complexes containing arsino(phosphino)methanes as ligands

U. Schmidt, K. Ilg and H. Werner, J. Chem. Soc., Dalton Trans., 2000, 1005 DOI: 10.1039/B001237H

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