Issue 19, 2000
From the journal:

Chemical Communications

Development of a family of β-amino alcohol ligands with two stereocenters for highly efficient enantioselective trimethylsilylcyanation of aldehydes

Jing-Song You,†a   Han-Mou Gau*a  and  Michael C. K. Choi*b  

* Corresponding authors

a Department of Chemistry, National Chung-Hsing University, Taichung, Taiwan
E-mail: hmgau@dragon.nchu.edu.tw

b Union Laboratory of Asymmetric Synthesis and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong

Abstract

The asymmetric addition of Me3SiCN to aldehydes catalyzed by titanium(IV) complexes of N-sulfonylated derivatives of β-amino alcohols gave excellent ee’s up to 96% ee.

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Article information

DOI
https://doi.org/10.1039/B006128J
Article type
Communication
Submitted
28 Jul 2000
Accepted
30 Aug 2000
First published
21 Sep 2000

Chem. Commun., 2000, 1963-1964

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Development of a family of β-amino alcohol ligands with two stereocenters for highly efficient enantioselective trimethylsilylcyanation of aldehydes

J. You, H. Gau and M. C. K. Choi, Chem. Commun., 2000, 1963 DOI: 10.1039/B006128J

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