Issue 19, 2000
From the journal:

Chemical Communications

Stabilised (H2)Al–E(H)R species, E = P or As, R− = C(SiMe3)2- (6-Me-2-pyridyl)−

Philip C. Andrews,a   Colin L. Raston*a  and  Brett A. Robertsa  

* Corresponding authors

a Department of Chemistry, Monash University, Clayton, Melbourne, Victoria, Australia.
E-mail: c.raston@sci.monash.edu.au

Abstract

Reaction of RECl2 (R− = C(SiMe3)2(6-Me-2-pyridyl)−, E = P or As) with LiAlH4 in THF affords directly bonded aluminium hydride–pnictide hydride complexes as weakly associated hydride bridged dimers, [RE(H)–Al(H)2]2; a strong solvent dependency of these reactions, which had previously been observed with the formation of the disecondary diphosphane in Et2O (E = P), is further confirmed by the formation of RAsH2 from RAsCl2 and LiAlH4 in Et2O.

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Article information

DOI
https://doi.org/10.1039/B003990J
Article type
Communication
Submitted
12 May 2000
Accepted
15 Aug 2000
First published
21 Sep 2000

Chem. Commun., 2000, 1961-1962

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Stabilised (H2)Al–E(H)R species, E = P or As, R− = C(SiMe3)2- (6-Me-2-pyridyl)−

P. C. Andrews, C. L. Raston and B. A. Roberts, Chem. Commun., 2000, 1961 DOI: 10.1039/B003990J

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