Issue 17, 2000
From the journal:

Chemical Communications

Highly selective anodic monofluorination of 4-arylthio-1,3-dioxolan-2-ones: a marked

Hideki Ishii,a   Norihisa Yamadaa  and  Toshio Fuchigami*a  

* Corresponding authors

a Department of Electronic Chemistry, Tokyo Institute of Technology, Nagatsuta, Midori-ku, Yokohama, Japan

Abstract

This is the first example of a solvent effect on fluorinated product selectivity; anodic fluorination of 4-arylthio-1,3-dioxolan-2-ones in CH2Cl2 containing a fluoride supporting electrolyte using an undivided cell provided the fluorodesulfurization product, 4-fluoro-1,3-dioxolan-2-one preferentially while anodic fluorination in DME resulted in α-fluorination, without desulfurization, selectively.

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Article information

DOI
https://doi.org/10.1039/B004652N
Article type
Communication
Submitted
12 Jun 2000
Accepted
17 Jul 2000
First published
08 Aug 2000

Chem. Commun., 2000, 1617-1618

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Highly selective anodic monofluorination of 4-arylthio-1,3-dioxolan-2-ones: a marked solvent effect on product selectivity

H. Ishii, N. Yamada and T. Fuchigami, Chem. Commun., 2000, 1617 DOI: 10.1039/B004652N

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