Issue 16, 2000

Intramolecular [2+2] photocycloadditions as an approach towards the bicyclo[2.1.1]hexane substructure of solanoeclepin A

Abstract

The synthesis of a tricyclic substructure of solanoeclepin A is described. The key step involves an intramolecular [2+2] photocycloaddition between a dioxinone and a tetrasubstituted bicyclic alkene providing the strained bicyclo[2.1.1]hexane moiety.

Supplementary files

Article information

Article type
Communication
Submitted
09 May 2000
Accepted
20 Jun 2000
First published
14 Jul 2000

Chem. Commun., 2000, 1463-1464

Intramolecular [2+2] photocycloadditions as an approach towards the bicyclo[2.1.1]hexane substructure of solanoeclepin A

R. H. Blaauw, J. Brière, R. de Jong, J. C. J. Benningshof, A. E. van Ginkel, F. P. J. T. Rutjes, J. Fraanje, K. Goubitz, H. Schenk and H. Hiemstra, Chem. Commun., 2000, 1463 DOI: 10.1039/B003755I

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