C60F18O, the first characterisedintramolecular fullerene ether

Olga V. Boltalina; Benoit de La Vaissière; Patrick W. Fowler; Peter B. Hitchcock; John P. B. Sandall; Pavel A. Troshin; Roger Taylor

doi:10.1039/B003753M

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C₆₀F₁₈O, the first characterised intramolecular fullerene ether

Olga V. Boltalina,^a Benoit de La Vaissière,^b Patrick W. Fowler,^b Peter B. Hitchcock,^c John P. B. Sandall,^b Pavel A. Troshin^a and Roger Taylor^c

Author affiliations

^a Chemistry Department, Moscow State University, Moscow, Russia

^b School of Chemistry, Exeter University, Stocker Road, Exeter, UK

^c The Chemistry Laboratory, CPES School, Sussex University, Brighton, UK

Abstract

A single-crystal X-ray structure determination of the main isomer of C₆₀F₁₈O shows it to be an intramolecular fullerene ether rather than an epoxide, and thus the first example of an oxa-homo[60]fullerene.

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Supplementary files

Crystal structure data TXT (35K)

Article information

DOI: https://doi.org/10.1039/B003753M
Article type: Communication
Submitted: 10 May 2000
Accepted: 12 Jun 2000
First published: 30 Jun 2000

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Chem. Commun., 2000, 1325-1326

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C₆₀F₁₈O, the first characterised intramolecular fullerene ether

O. V. Boltalina, B. de La Vaissière, P. W. Fowler, P. B. Hitchcock, J. P. B. Sandall, P. A. Troshin and R. Taylor, Chem. Commun., 2000, 1325 DOI: 10.1039/B003753M

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