Issue 10, 2000
From the journal:

Chemical Communications

Vapor phase Beckmann rearrangement of cyclohexanone oxime over a novel tantalum pillared-ilerite

Younghee Ko,a   Myung Hun Kim,a   Sun Jin Kim,a   Gon Seo,b   Mi-Young Kimb  and  Young Sun Uh*a  

* Corresponding authors

a Materials Chemistry Research Center, Korea Institute of Science and Technology, PO Box 131, Cheongryang, Seoul 130-650, Korea.
E-mail: uhyoung@kistmail.kist.re.kr

b Department of Chemical Technology, Chonnam National University, Kwangju 500-757, Korea

Abstract

The vapor phase Beckmann rearrangement of cyclohexanone oxime has been studied using a novel tantalum pillared-ilerite as catalyst: the cyclohexanone oxime conversion rate reaches 97.1% and the selectivity for ε-caprolactam is up to 89.1% at 350 °C.

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Article information

DOI
https://doi.org/10.1039/B001466O
Article type
Communication
Submitted
22 Feb 2000
Accepted
04 Apr 2000
First published
27 Apr 2000

Chem. Commun., 2000, 829-830

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Vapor phase Beckmann rearrangement of cyclohexanone oxime over a novel tantalum pillared-ilerite

Y. Ko, M. H. Kim, S. J. Kim, G. Seo, M. Kim and Y. S. Uh, Chem. Commun., 2000, 829 DOI: 10.1039/B001466O

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