When a water molecule can act as a proton acceptor during the critical H–H bond heterolytic dissociation step of formaldehyde hydrogenation, the barrier drops—an observation which links dihydrogen activation chemistry to hydride transfer at a detailed molecular level.
Dipolar H2 activation by H2O
E. L. Øiestad and E. Uggerud, Chem. Commun., 2000, 831 DOI: 10.1039/B001209M
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