The paramagnetic, heterometallic manganese cubanes [{E2(NCy)4}(MnCp)2] (Cy = C6H11, Cp = C5H5, E = As, Sb)

Alan Bashall; Michael A. Beswick; Helmut Ehlenberg; Sara J. Kidd; Mary McPartlin; Julie S. Palmer; Paul R. Raithby; Jeremy M. Rawson; Dominic S. Wright

doi:10.1039/A910196I

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

The paramagnetic, heterometallic manganese cubanes [{E₂(NCy)₄}(MnCp)₂] (Cy = C₆H₁₁, Cp = C₅H₅, E = As, Sb)Electronic supplementary information (ESI) available: plots of the effective magnetic moments of 1 and 2 as a function of temperature. See http://www.rsc.org/suppdata/cc/a9/a910196i/

Alan Bashall,^a Michael A. Beswick,^b Helmut Ehlenberg,^c Sara J. Kidd,^b Mary McPartlin,^a Julie S. Palmer,^b Paul R. Raithby,^b Jeremy M. Rawson^b and Dominic S. Wright*^b

Author affiliations

* Corresponding authors

^a School of Chemistry, University of North London, London, UK

^b Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cus.cam.ac.uk

^c Department of Physics, Cavendish Laboratory, University of Cambridge, Madingley Road, Cambridge, UK

Abstract

The heterometallic cubanes [{E₂(NCy)₄}(MnCp)₂] (E = Sb 1, As 2; Cy= C₆H₁₁, Cp= C₅H₅) are the first examples of complexes in which a paramagnetic metal ion has been incorporated into a p block ligand framework.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/A910196I
Article type: Communication
Submitted: 17 Dec 1999
Accepted: 23 Mar 2000
First published: 13 Apr 2000

Download Citation

Chem. Commun., 2000, 749-750

Permissions

Request permissions

The paramagnetic, heterometallic manganese cubanes [{E₂(NCy)₄}(MnCp)₂] (Cy = C₆H₁₁, Cp = C₅H₅, E = As, Sb)

A. Bashall, M. A. Beswick, H. Ehlenberg, S. J. Kidd, M. McPartlin, J. S. Palmer, P. R. Raithby, J. M. Rawson and D. S. Wright, Chem. Commun., 2000, 749 DOI: 10.1039/A910196I

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.