The rhodium catalysed addition of pinacolborane to aminopropyl vinyl ethers gave selective formation of the corresponding alkenylboronate esters while palladium or platinum complexes catalysed the hydroamination of aminopropyl vinyl ether to give tetrahydro-2-methyl-1,3-oxazine.
Metal catalysed addition of B–H and N–H bonds to aminopropyl vinyl ethers
C. M. Vogels, P. G. Hayes, M. P. Shaver and S. A. Westcott, Chem. Commun., 2000, 51 DOI: 10.1039/A908206I
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