Vanadium [dicyanoperfluorostilbene]2·yTHF: a molecule-based magnet with Tc ≈ 205 KElectronic supplementary information (ESI) available: preparation and spectral data for α,α′-dicyanoperfluorostilbene. See http://www.rsc.org/suppdata/cc/a9/a907535f/
Abstract
A new radical anionic bridging ligand, derived from the in situ reduction of α,α′-dicyanoperfluorostilbene, is reported to support ferrimagnetic ordering below 205 K in a three-dimensional vanadium-based coordination polymer.