The use of a C3 complex bearing three imidazolate groups as a ‘building block’ allowed us to synthesize an infinite corrugated two-dimensional (2D) low-spin Fe(III)–high-spin Mn(II) polymer exhibiting weak ferromagnetic intralayer interaction through imidazolate bridge.
A polymeric, layered bimetallic Mn(II)Fe(III) imidazolate network; crystal structure and magnetic properties
F. Lambert, J. Renault, C. Policar, I. Morgenstern-Badarau and M. Cesario, Chem. Commun., 2000, 35 DOI: 10.1039/A907068K
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