The title cation is found to exhibit the lowest Marcus intrinsic reactivity known so far for a carbon acid; this situation is shown to reflect a rate-limiting hydration/dehydration reaction of the aldehyde functionality.
G. Moutiers, Y. X. Peng, A. Peignieux, M. J. Pouet and F. Terrier, J. Chem. Soc., Perkin Trans. 2, 1999, 1287 DOI: 10.1039/A903667I
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