Novel multi-layered ‘rolled-paper-like’ silica was prepared by using the aggregate of an azacrown-appended cholesterol derivative as a template for the sol–gel polymerization of tetraethoxysilane: the metal bound to the azacrown moiety was thereby deposited in the interlayer space.
J. Hwa Jung, Y. Ono and S. Shinkai, J. Chem. Soc., Perkin Trans. 2, 1999, 1289 DOI: 10.1039/A903425K
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