An one-pot TiCl4 initiated assemblage of polyfunctional compounds via a sequential coupling of p-TolSCl, 1-methoxycyclo-alkene, methyl vinyl ether and Sn- or Si-capped carbon nucleophile is shown to proceed with high diastereoselectivity at all newly created chiral centres.
M. I. Lazareva, Y. K. Kryschenko, R. Caple, V. G. Young and W. A. Smit, Mendeleev Commun., 1999, 9, 24 DOI: 10.1070/MC1999v009n01ABEH001044
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